Watch Demi Lovato and Nick Jonas Blast the hits in 'Carpool Karaoke'

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Watch Demi Lovato Put Nick Jonas' Dating Life on Blast During 'Carpool Karaoke!'

Nick Jonas and Demi Lovatohave shared many rides in the 10 years they've been friends. None, however, have been quite like their trip with James Corden.

The Late Late Show host was at his singing and probing best as he took the wheel for a "Carpool Karaoke" session through Los Angeles with the pop star pair.

Nick Jonas & Demi Lovato Will Embark on Joint Tour

When Corden wasn't grilling Lovato and Jonas about their luck in love, the trio was belting out Lovato's "Heart Attack" and "Cold Stone," Jonas' "Close," and "Jealous" and DNCE's "Cake By The Ocean."

Corden didn't waste any time exploring the nature of the Jonas-Lovato relationship. "I don't know if you've noticed by I kinda go for older guys, no offense," responded Lovato, looking in Jonas' direction.

Lovato then teased Jonas by exploring his dating life. "Cyrus, Gomez, Cyrus, Gomez and then I don't know what else happened," she said, as a clearly-embarrassed Jonas asked to change subject. Tough luck. Corden then asked about Jonas' purity ring phase? Jonas, responding to the question of whether he'd been tied up, discussed being "literally chained to the wall" as he once performed a song in a gay club.

James Corden Shares His 'Carpool Karaoke' Wishlist

Corden used the occasion to audition for a part in Jonas and Lovato's joint Future Now tour, which kicks off next month. The British funnyman was put through his paces as they stopped the car for an impromptu busking stint with Lovato's "Confident," to the delight of dozens of onlookers. Watch the clip below.

Check out more from Corden in the gallery below!

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James Corden Late Late Show Premiere
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Watch Demi Lovato and Nick Jonas Blast the hits in 'Carpool Karaoke'
LOS ANGELES - MARCH 22: James Corden steps on stage for the first episode of The Late Late Show with James Corden, premiering Monday, March 23 (12:37 1:37 AM, ET/PT) on the CBS Television Network. (Photo by Monty Brinton/CBS via Getty Images)
LOS ANGELES - MARCH 22: James Corden chats with his first guests, Tom Hanks and Mila Kunis, on The Late Late Show with James Corden, premiering Monday, March 23 (12:37 1:37 AM, ET/PT) on the CBS Television Network. (Photo by Monty Brinton/CBS via Getty Images)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured L-R: Reggie Watts and James Corden (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured L-R: James Corden and Reggie Watts (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES, CA - MARCH 06: Actor/host James Corden puts up his own billboard for CBS Television Network's 'The Late Late Show' on March 6, 2015 in Los Angeles, California. (Photo by Alberto E. Rodriguez/Getty Images)
LOS ANGELES, CA - MARCH 06: James Corden puts up billboard for 'The Late Late Show' held on March 6, 2015 in Los Angeles, California. (Photo by Michael Tran/FilmMagic)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured: Reggie Watts (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured: James Corden (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured: James Corden (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES - MARCH 23: 'The Late Late Show with James Corden' -- James Corden and Reggie Watts tape the opening titles for 'The Late Late Show with James Corden,' which debuts Monday, March 23 (12:37 -- 1:37 AM, ET/PT) on the CBS Television Network. Pictured L-R: Reggie Watts and James Corden (Photo by Neil Jacobs/CBS via Getty Images)
LOS ANGELES - JANUARY 23: 'The Late Late Show with James Corden' - James Corden takes over as host of THE LATE LATE SHOW on Monday, March 23 (12:37 - 1:37 AM, ET/PT) on the CBS Television Network. (Photo by Art Streiber/CBS via Getty Images)
Yotubazos:"James Corden Wins the Golden Ticket to Host the Late Late Show"->:http://t.co/BPMCtcStUk http://t.co/rZ2C2JKnBR
James Corden makes Mila Kunis admit she has married Ashton Kutcher on Late Late show premiere http://t.co/CX2brE8VpT http://t.co/Jn5Y2aiZ0R
James Corden Gets Punched by @JayLeno in Star-Studded #LateLateShow Debut (Video) http://t.co/2oXnsgnDU4 @JKCorden http://t.co/24UECSX9RG
James Corden debuts on US chat show The Late Late Show tonight. He's received this card from @JayLeno http://t.co/GtA4B8PlNE
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